Gears Of War springs to mind straight away here. I own a PS3 now, and when it came out I had a PS2, so I couldn't buy it without having to buy an Xbox.
I remember when I was in sixth form at school, and me and my mate would go to his house to play some GOW during free lessons. We always did Co-op campaign, which was awesome. Those were the only times I got to play it, and almost considered getting an Xbox solely for it. I really wish it wasn't an Xbox exclusive
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